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1 article(s) from Offermans, Willem K.

Surprisingly facile CO₂ insertion into cobalt alkoxide bonds: A theoretical investigation

Willem K. Offermans,
Claudia Bizzarri,
Walter Leitner and
Thomas E. Müller

Beilstein J. Org. Chem. 2015, 11, 1340–1351, doi:10.3762/bjoc.11.144

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Scheme 1: Reaction of carbon dioxide with epoxide to yield alternating polycarbonates, polyethercarbonates or...

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Scheme 2: Epoxide and CO₂ copolymerisation by homogeneous Cr(III)– and Al(III)–salen complexes.

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Figure 1: The tri-coordinated di-iminate zinc–alkoxide complex [(BDI)ZnOCH₃].

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Scheme 3: Heterogeneous zinc dicarboxylates for the copolymerisation of CO₂ and epoxides. (* = End group of p...

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Scheme 4: Backbiting mechanism for the formation of cyclic carbonates.

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Scheme 5: Two-step pathway for the cycloaddition of propylene oxide and CO₂ in the ionic liquid 1-butyl-3-met...

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Scheme 6: Formation of copper(I) cyanoacetate for the activation of CO₂.

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Scheme 7: Activation of CO₂ by nucleophilic attack of bromide in the Re(I)-catalysed cycloaddition.

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Scheme 8: Direct catalytic carboxylation of aliphatic compounds and arenes by rhodium(I)– and ruthenium(II)–p...

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Scheme 9: Insertion of carbon dioxide into a metal–oxygen bond via a cyclic four-membered transition state. R...

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Scheme 10: Facile CO₂ uptake by zinc(II)–tetraazacycloalkanes.

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Figure 2: The [(2-hydroxyethoxy)Co^III(salen)(L)] complex chosen as catalyst model for the calculations; 1: R¹...

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Figure 3: The two most relevant configurations of [(2-hydroxyethoxy)Co^III(salen)(L)] complexes. The left-hand...

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Figure 4: Carbon dioxide insertion into the cobalt(III)–alkoxide bond of [(2-hydroxyethoxy)Co^III(salen)(L)] c...

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Figure 5: Energy relationship between the activation barrier and the reaction energy of the CO₂ incorporation...

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Published 31 Jul 2015

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Surprisingly facile CO2 insertion into cobalt alkoxide bonds: A theoretical investigation

Surprisingly facile CO₂ insertion into cobalt alkoxide bonds: A theoretical investigation